UNIST Discovers Waste Gas to Biofuel Catalyst

Joanna Schroeder

A research team led by Professor Jae Sung Lee of Energy and Chemical Engineering at UNIST has discovered a new way to make biofuels directly from carbon dioxide. The team has produced road ready diesel through a direct CO2 conversion to liquid transportation fuels by reacting with renewable hydrogen generated through solar water splitting. The research was published in the journal Applied Catalysis B: Environmental.

The sample on the left is the new delafossite-based catalyst used in the reaction between CO2 and H2 generated by solar water splitting. Shown on the right is diesel, produced by the reaction.

The sample on the left is the new delafossite-based catalyst used in the reaction between CO2 and H2 generated by solar water splitting. Shown on the right is diesel, produced by the reaction.

According to Lee, traditional catalysts used for H2 with CO2 reactions mostly rely on low molecular weight substances such as methane or methanol. These low value catalysts provide low CO2 reduction effects. However, the research team has found the new delafossite-based catalyst composed of affordable copper and steel, converts CO2 into liquid hydrocarbon-based fuels (e.g., diesel fuel) in one single step. The resulting fuels can be used by trucks and buses with no modifications. The catalyst causes a reaction between CO2 emissions of industrial plants and H2 generated from solar hydrogen plant with diesel as the result.

“Diesel fuels have longer chain of carbon and hydrogen atoms, compared to mathanol and methane,” says Yo Han Choi, the first author of the research. “Using delafossite-CuFeO2 as the catalyst precursor, we can create longer carbon chains and this would allow for the production of diesel.”

%e1%84%8b%e1%85%b5%e1%84%8c%e1%85%a2%e1%84%89%e1%85%a5%e1%86%bc-%e1%84%80%e1%85%ad%e1%84%89%e1%85%ae%e1%84%90%e1%85%b5%e1%86%b7_main-800x448This direct CO2-FT synthesis, explains Yo Han Choi, is different from the German car maker Audi’s CO2-to-dielsel conversion process that involves two steps – reverse water gas shift (RWGS) reaction to CO followed by CO Fisher-Tropsch (FT) synthesis.

The researchers believe their new discovery holds the potential to revolutionize the auto industry in part due to its two major benefits: the process removes climate-change causing CO2 from the atmosphere and the resulting diesel/biofuel can be used an an alternative to petroleum-based transportation fuels.

Professor Lee adds, “We believe the new catalyst breaks through the limitation of CO2-based FT synthesis and will open the avenue for new opportunity for recycling CO2 into valuable fuels and chemicals.”

advanced biofuels, Carbon, Research, Waste-to-Energy

KAAPA Ethanol Ravenna Joins RFA

Joanna Schroeder

kaapa-ethanol-logoKAAPA Ethanol Ravenna has joined the Renewable Fuels Association (RFA). The ethanol company, KAAPA Ethanol Holdings, recently closed on its purchase of the Abengoa Bioenergy ethanol facility located in Ravenna, Nebraska. The company also owns an ethanol facility in Minden, Nebraska. With the addition of Ravenna, KAAPA’s total ethanol production is 170 million gallons per year. This is the KAAPA’s second producer membership to RFA.

“We are pleased that KAAPA’s experience already being an RFA member made it an easier choice to add their second facility to our roster,” said RFA President and CEO Bob Dinneen. “The hardworking farmer-owners of KAAPA Ethanol Holdings are providing consumers with ethanol, the lowest cost, cleanest-burning and highest octane source in the world. We welcome KAAPA’s second ethanol plant to our membership and look forward to its participation and input.”

“RFA has a stellar reputation of providing outstanding member services, technical analyses and policy support, which benefits our entire ethanol industry and directly affects our two ethanol plants,” said KAAPA Ethanol Holdings CEO Chuck Woodside. “RFA continues to be at the forefront of promoting even further growth of our industry through higher ethanol blends, while simultaneously combatting misinformation propagated by our critics. We are thrilled to add another plant to our RFA membership and look forward to future growth opportunities under the RFA umbrella.”

Ethanol, Ethanol News, RFA

Iowa Biodiesel Board Leader Elected to NBB Board

Joanna Schroeder

chad-stone-2014This week, Iowa Biodiesel Board (IBB) former leader Chad Stone, with the Renewable Energy Group (REG), was elected to a leadership position with the National Biodiesel Board (NBB). Stone recently served as the immediate past chair of IBB. The election took place in St. Louis, Missouri last week during NBB’s annual fall meeting. NBB’s board is comprised of 15 governing board members, including four executive officers.

“The year ahead is important as we will be in a vastly changed political landscape, and we’ll be working hard to continue to grow the volumes of biomass-based diesel,” Stone said. “I’m optimistic for the future of NBB, and for America’s Advanced Biofuel. I look forward to serving as an officer in this important national organization.”

Two other Iowans were also elected to positions on the NBB Board. Ron Heck, soybean farmer from Perry, Iowa who is currently serving as IBB treasurer and representing the Iowa Soybean Association on the IBB board, along with Steve Nogel of AGP, a biodiesel producer with biorefineries in Sergeant Bluff and Algona, Iowa.

“The fact that Iowa is the leading biodiesel-producing state is reflected in the makeup of the national organization’s leadership,” said Grant Kimberley, executive director of IBB. “This will be a critical time to maintain the momentum of this American manufacturing industry, and Chad’s leadership will help guide the national effort.”

advanced biofuels, Biodiesel, NBB

DuPont & MIAVIT Forge Biogas Enzyme Supply Contract

Joanna Schroeder

DuPont Industrial Biosciences and MIAVIT GmbH have forged a biogas enzyme supply contract. An integral part of the agreement will be DuPont supplying enzymes for incorporation in MIAVIT biogas boosting products. According to DuPont, its enzyme technology is proven to improve several production areas including biogas yields and process robustness. This, says DuPont, will increase revenues and profitability.

Enzymes break down large polymers into smaller sugars and amino acids more suitable for biogas-producing organisms.

Enzymes break down large polymers into smaller sugars and amino acids more suitable for biogas-producing organisms.

MIAVIT will be adding DuPont’s FIBREZYME® G4 enzyme biotechnology for inclusion in its MiaMethan® ProCut, a new biogas ingredient for the ag sector. The product, says MIAVIT, improves the breakdown of difficult to digest materials enabling more efficient biogas conversion. FIBREZYME G4 comes in a powder format to help reduce viscosity of hard to digest materials by over 60 percent, according to DuPont, thus enabling faster processing time.

“We are constantly innovating to offer our customers the latest technology to improve profitability and opportunity in the marketplace,” said Franz Otten, managing director of Sales at MIAVIT. “As new technology, like FIBREZYME® from DuPont, comes online, we see tremendous opportunity for our customers to improve efficiency and yields. This, in turn, provides the emerging biogas industry a new revenue stream, particularly for rural and farm communities, from materials that would ordinarily go to waste – reducing damaging environmental impacts and expanding renewable options for power generation.”

Enzymes are an important element to more effective and efficient biogas production. They serve to accelerate the breakdown of materials such as animal and food and farm waste, resulting in sugars and amino acids more pliable for conversion into biogas. The resulting renewable methane biogas can then to used to generate electricity or can be compressed and transported into a pipeline gas grid.

“DuPont is focused on continuous innovation for our customers,” added Conrad Burke, global marketing director at DuPont Industrial Biosciences. “Customers can expect this technology to increase biogas production, improve biogas quality, shorten process time and reduce the amount of feedstock required – all backed by our decades of experience in the global industrial enzyme and renewable energy businesses.”

This is not DuPont’s first enzyme entry for the biogas market. Back in July the company launched OPTIMASH® AD-100, a new liquid enzyme that DuPont says has been shown to produce up to a 13 percent increase in biogas yields in anaerobic digesters.

biodigester, biogas, enzymes

GRFA Calls For Global #Biofuels Commitment at COP22

Joanna Schroeder

With COP22 under way, the Global Renewable Fuels Alliance (GRFA) is calling for a global commitment to biofuels as countries transition to low-carbon economies. Bliss Baker, GRFA president, says that biofuels such as ethanol are proven to reduce greenhouse gas emissions (GHG) from 40 percent to 90 percent as compared to fossil fuels.

GRFA logoPrior to COP22, the United Nations released an Environment Programme (UNEP) report that determined current global emission reduction commitments will fall far short of international temperature targets. The report called for global emissions reductions of at least a quarter by 2030.

“Negotiators are confronting the enormous challenge of identifying achievable policy options that will significantly, and affordably, reduce GHG emissions.” Baker said. “Biofuels represent the only commercially viable technology available to significantly offset emissions in the global transport sector. In 2014 alone global ethanol production and use reduced GHG emissions by 169 million tonnes CO2 equivalent.” he added.

Today nearly half the world’s oil consumption is by the global transportation sector that accounts for 25-30 percent of global emissions. According to GRFA, this sector also has the lowest renewable energy share. In light of this, the organization is highlighting studies that find significant potential for increased biofuel use.

“In order to achieve international targets, the negotiations at COP22 must result in decisive support for biofuels production and technology development.” added Baker. “To fully achieve the huge potential of biofuels to cut global transport emissions, the historic political commitments of the past year have to result in concrete, and ambitious action.”

biofuels, Ethanol

#Ethanol Report on Food Prices

Cindy Zimmerman

ethanol-report-adThe cost of Thanksgiving dinner this year is less than it was a year ago, with turkey leading the way in lower prices. At the same time, the amount of corn used to make ethanol will set a new record in 2016, up roughly 3% from last year. A new analysis from Informa Economics takes a look at food prices over the past ten years in the era of ethanol and finds food versus fuel is still a myth, even though ethanol detractors continue to bring it up.

In this Ethanol Report, Renewable Fuels Association senior vice president Geoff Cooper talks about the analysis and why it “knocks the stuffing out of ‘Food vs. Fuel’ turkeys”: Ethanol Report on Food Prices

Audio, Ethanol, Ethanol News, Ethanol Report, food and fuel, Food prices, RFA, RFS

New Biodiesel Board in Place

Cindy Zimmerman

nbb-board-17Members of the National Biodiesel Board (NBB) members selected their leadership this week, electing six returning governing board members and one new member to serve in leadership roles, joining new NBB CEO Donnell Rehagen in moving the organization forward.

NBB members voted to fill seven board member spots:
• Greg Anderson, Nebraska Soybean Board
• Jennifer Case, New Leaf Biofuel, LLC
• Mike Cunningham, ASA
• Tim Keaveney, Hero BX
• Steven J. Levy, Sprague Operating Resources
• Mike Rath, Darling Ingredients, Inc.
• Ben Wooton, World Energy

Kent Engelbrecht, Ron Heck, Ed Hegland, Ron Marr, Steve Nogel, Amy Sigg Davis, Robert Stobaugh, and Chad Stone also continue to serve on the Governing Board. The board also took the opportunity to elect officers with Kent Englebrecht serving as the new chairman, Mike Cunningham as Vice Chairman, Greg Anderson as Treasurer and Chad Stone as Secretary.

“The biodiesel industry is fortunate to have a strong team of leaders from all sectors of the industry,” said Rehagen. “The membership is united, optimistic, and will continue to grow into the future under the direction of the board.” During the annual fall membership meeting NBB members discussed a number of important topics including the current state of federal policies impacting the industry, held meetings of standing committees, and began the annual program planning process.

Biodiesel, NBB

Ag Seems Positive With Trump Presidency

Jamie Johansen

zp-nh1Our latest ZimmPoll asked the question, “What will Trump presidency mean for ag?”

The election is over, however we are still discussing what a Trump Administration will not only mean for agriculture, but for our nation as a whole. NAFB hosted an agriculture “Reaction to Election” panel last week highlighting insights from key agricultural leader opinions. Remarks from those leaders fell into place with our recent poll results. An overwhelming majority feel a Trump presidency will equal positivity for ag.

Here are the poll results:

  • All good – 43%
  • All bad – 17%
  • Bad for exports – 9%
  • Nothing will change – 17%
  • I’m moving to Canada – 14%

Our new ZimmPoll is live and asks the question, What are you most thankful for this year?

As we come off the high from political discussion overload, this week we want to take it easy and think back over 2016. Thanksgiving is a time of reflection, a time to remember and give thanks. Share with us what tops your charts when it comes to thankfulness this year.

ZimmPoll

BioEnergy Bytes

Joanna Schroeder

  • BioEnergyBytesDF1Acting on behalf of North European Bio Tech Oy (NEB), St1 has begun the analysis and signed letters of intent with Alholmens Kraft and UPM on a sawdust-based ethanol plant in the Alholma industrial area in Pietarsaari. The planned production capacity of the plant is 50 million litres of advanced bioethanol per year. The Cellunolix® plant, which utilises sawdust and recycled wood, is planned for UPM’s Alholma industrial area. Alholmens Kraft and UPM would provide the project with the mill site’s services and commodities and where possible, would utilise the by-products of the ethanol production in their own processes.
  • Clean Energy Fuels Corp., has announced that the City of Torrance has awarded Clean Energy a new multiyear compressed natural gas (CNG) contract to fuel its fleet of vehicles. The six-year deal, which calls for 550,000 gasoline gallon equivalents, will enable the city to use Clean Energy’s Redeem™ brand of renewable natural gas (RNG), rated up to 70 percent cleaner than diesel and considered the cleanest transportation fuel available.
  • It’s been a year since President Obama and the leaders of 19 nations stood together in Paris to launch Mission Innovation (MI) to accelerate the pace of clean energy innovation and to support economic growth, energy access and security, and as an urgent and lasting global response to climate change with the goal of doubling public investment in clean energy research and development to reach $30 billion in five years. Members are taking another step forward with the announcement that the Obama Administration has created the Sustainable Biofuels Innovation Challenge – to develop ways to produce, at scale, widely affordable, advanced biofuels for transportation and industrial applications.
Bioenergy Bytes

USDA Releases $1.5M in BCAP for #Biomass Harvesting

Joanna Schroeder

Farmers and others who harvest biomass crops for renewable energy will have access to $1.5 million in FY2017 under the Biomass Crop Assistance Program (BCAP). The total funds available under the program for 2017 is $3 million with the other $1.5 allocated to growers who establish or maintain biomass crops to be used specifically for energy or biobased products.

bcap_logo_368“USDA investments in expanding biofuel feedstocks lay the foundation for more bioproducts made in rural America, supporting rural economic development, reducing carbon pollution and helping decrease our dependence on foreign energy,” said USDA’s Farm Service Agency (FSA) Administrator Val Dolcini.

Facilities seeking to be qualified by USDA to accept BCAP-funded biomass can begin enrollment Nov. 14 through Dec. 5, 2016. Also, between Jan. 9, 2017, through March 15, 2017, USDA will accept applications from foresters and farmers seeking incentives to remove biomass residues from fields or national forests for delivery to energy generation facilities. The retrieval payments are provided at match of $1 for $1, up to $20 per dry ton. Eligible crops include corn residue, orchard waste or diseased or insect-infested wood materials.

To enroll for BCAP funds click here. To contact your local FSA county office, click here.

advanced biofuels, biomass